Production of fire involves chain reaction as shown below.

In every step the energy released is not completely used in transforming substrate to product, the extra energy is added as the reaction goes on and it gets hot and bright.
Enzymes: Enzymes transform one type of substance to other. One enzyme molecule can easily transform a large amount of substances. This is one sort of amplification.
In biological system one excited enzyme molecule can transform thousands of other molecule in small time. This way signal which excite or activate a single molecule can be amplified. Fire usually amplifies in uncontrolled way but biological signal amplification is controlled.
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